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Figure 16.15 (A) Complete CA image server system architecture. The three Ethernet interfaces from each of the three modules are connected to the LAN, while only one Ethernet interface is active and forms only one IP address for the application. Two mirrored disks (mirrored Disk0 and mirrored Disk1) are connected to module A and module B through the UW (ultrawide) SCSI interface with fail-over mode. Two RAID controllers (RAID Cotl0 and RAID Cotl1) are connected to modules A and B through the UW SCSI interface with fail-over mode. Two DLT controllers (DLT drive0 and DLT drive1) are connected to modules A and B through the UW SCSI interface with fail-over mode. (See the References at the end of the chapter for how this fault-tolerant architecture performs fail over under various conditions.) UPS: uninterruptible power supply, 100 BT: 100 base T Ethernet. (B) CA image server connected to the PACS simulator shown during RSNA Scienti c Exhibit of 2001 and also at SPIE 2002. The system was demonstrated annually at RSNA until 2005. The simulator consists of the modularity simulator (left) and a gateway (middle), TMR (see Fig. 16.12B), and two workstations (right). The RAID and LTD library are not shown in the gure. (C) Schematic of the CA image server connected to the PACS simulator system (see 28) shown during the RSNA Scienti c Exhibit of 2001. A similar setup was used as the ASP PACS backup archive and other imaging informatics research and development projects at the IPILab, USC until 2007. It was replaced by the Data Grid discussed in 21.

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E1cB Mechanism Reaction The E1cB mechanism has the same features as the E2 mechanism except that proton abstraction by the base proceeds essentially to completion prior to departure of the leaving group A variant of this mechanism may intervene whenever the leaving group is a poor leaving group or an exceptionally stable carbanion may be formed (ie, due to the presence of Z substituents in addition to the polar s bond and/or a hybridization e ect) The factors which lead to stabilization of carbanions have been discussed in 7 E1 Elimination Reaction The rate-determining step of the E1 elimination reaction is precisely the same as previously discussed for the SN 1 reaction The interaction diagram for the C H bond and an adjacent carbocationic center is shown in Figure 106b.

6.1, 5.1, 2.1, 2.0

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Because the s and s C H bond orbitals are equally spaced relative to the energy of the p orbital at the cationic site, the LUMO energy is approximately the same as the energy of the unperturbed cationic p orbital Reactivity with Lewis bases remains very high but is reduced somewhat by delocalization of the orbital (smaller coe cient on the p orbital) Notice that the presence of the adjacent C H bond results in stabilization of the carbocation by a lowering of the energy of the sCH orbital Concomitant delocalization of the C H bonding electrons is accompanied by weakening of the C H bond and partial bond formation between the H and the C at the cationic site Hydride transfer may result if this is energetically favorable The most probable course of the reaction with a Lewis base is formation of a s bond at the cationic site.

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This is a representation of how the line is stored in the AutoCAD drawing database. AutoLISP returned one large list that contains 12 smaller lists. Each of the smaller lists is referred to as a group indexed by the first element. The entity name is in group 1. Each of the initial numbers in the small lists represents a different quality of the line. These numbers are called object group codes. The object group codes used most often are listed in Table 35-2.

However, there is a possibility of attack at the H end of the C H bond, and this mode may be enhanced if the base is a ``good'' Lowry Bronsted base (forms a strong bond to H) Both addition of the nucleophile to C and proton abstraction are reversible The equilibrium may often be channeled toward proton abstraction by removal of the more volatile ole n by distillation..

9984357, EIA 0103674, EIA 0120934, ANI 0335244, CNS 0709329, CNS 0305495, CNS 0426354, and IIS 0430826, and by the Department of Energy via the Grant No. DE-FG02-06ER54857.

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