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Process Issues By proper selection of catalysts and etching solutions, the catalyst on the hole walls survives during the etching operation, posing no problem in the subsequent plating step. In step 6, plating resist can be applied by screen printing when the circuit density is not so high. When the density becomes higher, dry film or liquid photoimageable resist can be used. Liquid resist can be applied by open screen coating, roller coating, or curtain coating. In some cases, step 6 can be bypassed when sideways line growth is not a problem (Fig. 31.3). In such a case, the plating speed is reduced by 20 to 30 percent, from the normal speed of 2.0 to 2.5 mm, in order to avoid copper deposition on unwanted areas (bare laminate areas). Conductors must be made narrower than the intended final width at the design stage to compensate for the side growth.

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Fig 612: A range of shaft and housing tolerance with respect to bearing tolerance [6]

Then, since the external Interrupt0 has a higher priority than the UART interrupts, the ISR corresponding to the external Interrupt0 will be executed, and after that, the ISR for the UART interrupt will execute The lowest program memory addresses are assigned for reset and interrupt vectors For the AT90S2313, these vectors are corresponding program memory addresses as follows:.

31.5.3 Fine-Pitch Components As the lead pitch of multipin devices becomes narrower than 20 mil (0.5 mm), bridging between adjacent pads during plating can occur even when plating resist is placed between them. As a result, the practitioners of the partly additive process are abandoning this process and converting to the panel-plate additive method based on the experiences they gained from practicing partly additive technology.

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Chemical reactions which take place in electroless plating have been treated well in the literature.4,21 However, they are discussed again here because some of the due comments are relevant to the chemistry of electroless plating.

Electroless Plating Solution Chemical Reactions Main ingredients of most electroless plating bath formulations consist of NaOH HCHO CuSO4 EDTA pH adjustment Reducing agent (formaldehyde) Source of copper iron Cheleting agent

31.6.1.1 Copper Deposition. The chemical reaction of copper deposition may be represented by Cu(EDTA)2 + 2HCHO + 4OH Cu0 + H 2 + 2H2O + 2CHOO + EDTA4 (31.1)

Selection of rolling element bearings [5]

Under the alkaline pH condition, the cupric ions would normally combine with OH to produce cupric hydroxide [Cu(OH)2], a useless precipitate. When a cheleting agent such as EDTA is added, it prevents cupric hydroxide formation by maintaining the Cu2+ in solution. Once the deposition of metallic copper starts through catalytic sites, the reaction in Eq. (31.1) continues because of the autocratic nature of the reaction. 31.6.1.2 Cannizzaro Reaction and Formaldehyde Concentration. While this main reaction, represented by Eq. (31.1), takes place, other undesirable side reactions proceed, also in

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competition with the reaction. One of the major difficulties is the lowering of formaldehyde concentration in the solution due to its disproportionate consumption in alkaline solution. This is known as the Cannizzaro reaction, which may be characterized by 2HCHO + OH CH 3OH + HCOO (31.2)

rjmp RESET rjmp EXT_INT0 rjmp EXT_INT1 rjmp TIM_CAPT1 rjmp TIM_COMP1 rjmp TIM_OVF1 rjmp TIM_OVF0 rjmp UART_RXC rjmp UART_DRE rjmp UART_TXC rjmp ANA_COMP

This reaction continues independently. Fortunately, methanol (CH3OH) one of the byproducts of the Cannizzaro reaction, tends to shift the equilibrium of the reaction in Eq. (31.2) to the left and thus prevents the decrease of formaldehyde concentration by an unproductive reaction. By controlling the plating conditions properly, the wasteful consumption of formaldehyde by the Cannizzaro reaction can be retained within 10 percent of the consumption in the reaction in Eq. (31.1). 31.6.1.3 Fehlings-Type Reactions. In addition to the Cannizzaro reaction, the following side reaction also competes for formaldehyde: 2Cu2 + + HCHO + 5OH Cu2O + HCOO + 3H 2O (31.3)

31.6.1.4 Other Formaldehyde-Related Reactions. Under conditions which would favor the Fehlings-type reaction [Eq. (31.3)], spontaneous decomposition of uncatalyzed plating solutions produces precipitation of finely divided copper with attended vigorous evolution of hydrogen gas. The finely divided copper produced is due to the disproportionate quantity of Cu2O under alkaline conditions: Cu2O + H 2 O Cu0 + Cu2 + + 2OH (31.4)

1 2 3 4 5 6 7 8 9

Furthermore, formaldehyde may act as a reducing agent for the cuprous oxide to produce metallic copper: Cu2O + 2HCHO + 2OH 2Cu0 + H2 + 2HCOO + H2O (31.5)

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.net core qr code generator

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.net core qr code generator

.net core qr code generator

.net core qr code generator

.net core qr code generator

.net core qr code generator

.net core qr code generator

.net core qr code generator

.net core qr code generator

.net core qr code generator